Modified titanium oxide (TiO2) nanocomposites and its array of applications: a review

Titania (TiO₂) has been the focus of attention of researchers since the first demonstration of its capability to generate the photocatalytic splitting of water into hydrogen and oxygen. However, there seems to be a recent surge in the research activity, involving modified TiO₂ nanoparticles (NP), which are considered to be more effective due to different physicochemical properties in comparison to unmodified fine particle analogs. Several strategies have been employed to modify TiO₂ to reduce recombination rates of photogenerated charge carriers to enhance the optimal functioning of TiO₂. Doping with cations and anions and coupling it with another semiconductor are the most well-known modification methods used. Titania nanocomposites are known to have a plethora of applications. Photoexcitation of these particles are seen to be extraordinarily effective in eliciting microbial death which makes it an attractive candidate for the manufacturing of antimicrobial coatings. On the other hand, TiO₂ induces the oxidation of various organic refractory compounds like tetracycline, sulfamethazine, and bisphenol. The photo-electrocatalytic oxidation technique which amalgamates the principle of photocatalysis and electrolysis serves as a newer, unswerving, and cost effective water treatment process. In the biomedical arena, use is now acknowledged for the photodynamic therapy of cancer, cell imaging, biological sensors, drug delivery system, and as endonucleases. In the commercial front, it is utilized in creams owing to its small particle size, which facilitates absorption through skin. It is also employed as ultraviolet blocking agents in sunscreen and commonly encountered as a brilliant white pigment in paint due to its brightness, high refractive index and resistance to discoloration. Its use in solar cells has also been reported. This review aims to encompass the new progress of modified TiO2 nanocomposites for efficient applications, emphasizing the future trends of TiO2 in arenas like healthcare, environment, biomedical, food, personal care, and pharmacy and also highlights the commercial implications of this promising nanomaterial.     

The politics of employment liability

Employment liability is an important check and balance against employee harm at work. In practice, however, an inadvertent consequence of employment liability is a potential shift in power from organizations to employees that affects subsequent managerial decision making. In this Incubator, we discuss behavioral and attitudinal ramifications of employment liability at work. Copyright © 2014 John Wiley & Sons, Ltd.     

三维点云基础上排土场垮塌影响范围研究

高台阶排土场下游常分布有居民区、厂房等,一旦垮塌,后果严重,因此完善的防治与应急准备工作十分关键,而排土场垮塌影响范围的预测是这些工作的重要前提依据。为提升高台阶排土场垮塌影响范围的预测准确性,需要获取准确的地形边界基础数据。通过利用三维激光扫描仪对新建排土场及其下游地形精细扫描,对获取的三维点云数据去噪、拼接、建模等处理,生成精度更高的数字高程模型与三维实体模型。在此基础上,结合新建高台阶排土场地质勘查与设计资料,建立颗粒离散元数值模型,利用PFC3D计算高台阶排土场垮塌影响范围,并与经验公式法计算结果对比分析,结果表明排土场颗粒离散元数值模型精度符合要求,可快速、准确地计算影响范围,从而为相关部门提供科学决策依据。     

保护层开采效果测评指标及应用研究

为深入分析保护层开采的实施效果,依据煤岩卸压变形理论和瓦斯运移特性,建立保护层开采测评指标体系,并选择淮南矿区对指标现场应用方法进行分析。研究结果表明:测评体系包括保护范围和保护效果两部分,其中,瓦斯压力、瓦斯含量、煤层透气性系数、煤层顶底板相对变形、瓦斯抽放量、突出指标的变化等因素可作为效果考察的现场测评指标。保护层开采后,应首先明确其保护范围,然后再对保护效果分别从煤体力学特性、煤层瓦斯特性和煤层开采动力特性3方面进行综合分析,按照现场实测值与指标临界值的对比,即可系统地定量评价保护层开采的效果。     

水污染侵权中因果关系的认定

水污染侵权中的因果关系成立与否决定着民事责任的有无,对受害人的利益影响甚巨,关于因果关系的理论纷繁复杂,水污染侵权中的因果关系认定难度更大,试图在分析各种学说的基础上找到认定水污染侵权中因果关系的可行方法。     

中国城市温室气体清单研究

介绍城市温室气体排放特征和国际城市温室气体清单研究进展,研究了全球城市化和城市CO2排放的强正相关性,以及中国城市清单方法研究起步较早但发展缓慢的特点。分析了城市温室气体清单相对国家清单的特征,即城市清单编制往往采用消费模式,区别于国家清单的生产模式;国际城市清单中往往包括了由于外调电和供暖产生的CO2排放,同时城市温室气体清单编制灵活性和针对性更强。针对我国城市温室气体清单研究的不足,提出了我国城市温室气体清单方法,强调中国城市采用尺度1+尺度2的范围,暂不考虑尺度3的范围,即生产+消费的混合模式,并且在城市市域温室气体排放研究的基础上,加强狭义城市温室气体排放水平的研究。选择北京市和纽约市,对比分析了两个城市CO2排放特征,结果显示,在确定的清单体系下,北京市和纽约市具有较好的可比性。纽约市的总排放量(尺度1+尺度2)略低于北京市排放量,人均排放量略高于北京市。     

Review of LCA studies of solid waste management systems – Part II: Methodological guidance for a better practice

Life cycle assessment (LCA) is increasingly used in waste management to identify strategies that prevent or minimise negative impacts on ecosystems, human health or natural resources. However, the quality of the provided support to decision- and policy-makers is strongly dependent on a proper conduct of the LCA. How has LCA been applied until now? Are there any inconsistencies in the past practice? To answer these questions, we draw on a critical review of 222 published LCA studies of solid waste management systems. We analyse the past practice against the ISO standard requirements and the ILCD Handbook guidelines for each major step within the goal definition, scope definition, inventory analysis, impact assessment, and interpretation phases of the methodology. Results show that malpractices exist in several aspects of the LCA with large differences across studies. Examples are a frequent neglect of the goal definition, a frequent lack of transparency and precision in the definition of the scope of the study, e.g. an unclear delimitation of the system boundaries, a truncated impact coverage, difficulties in capturing influential local specificities such as representative waste compositions into the inventory, and a frequent lack of essential sensitivity and uncertainty analyses. Many of these aspects are important for the reliability of the results. For each of them, we therefore provide detailed recommendations to practitioners of waste management LCAs.     

煤炭行业推行安全生产责任保险作用及问题探讨

为了减少事故及其造成的损失，使企业不致因灾后赔付而陷人困境和摆脱“企业赚钱，政府发丧”的怪圈，在煤炭行业推行安全生产责任保险，把商业保险模式引入安全生产领域，分散转移风险，并运用保险行业风险管理方法，规避、控制和管理风险，强化事故预防，以达到安全发展、可持续发展的目标。笔者在认真研究有关政策法规，搜集整理相关资料，实地凋研考察的基础上，结合我国煤炭行业安全生产以及煤炭行业责任风险管理现状，对我国煤炭行业推行安全生产责任保险的作用以及试点省市安全生产责任保险实施过程中遇到的问题进行了分析探讨。     

环保新思维：绿色保险

我国现在正处于环境事故高发期，而环境污染损害赔偿是企业，甚至是国家必须面对的现实问题。然而单凭企业承担责任是力所不能及的，最终不得不由国家买单，给国家带来沉重的负担。这种情况迫切需要建立环境污染损害责任保险机制，即绿色保险，把赔偿引向社会化。保险本身就是一种救灾形式，因为它能分散风险，减少损失。针对我国的具体情况，建立适宜的环境污染责任保险模式才能平衡发展与环境保护的关系、在全社会牢固树立生态文明理念。     

河南省煤化工行业环境风险等级划分研究

基于目前国家建立环境污染责任保险制度的规划需求和河南省当前新发展形势需要,选择以河南省典型高污染、高风险行业(即煤化工行业)为研究对象.在对相关理论进行分析的基础上,识别影响河南省煤化工行业的环境风险因子,并确定指标的评估标准(权重及评分结果).遵照指标体系的建立原则,采用层次分析法,从内在性和外在性两方面因素构建煤化工行业环境风险等级划分指标体系,进一步将评分结果与环境风险等级比对,最终将煤化工行业的环境风险等级划分为5个等级,为河南省环境污染责任保险制度的建立奠定基础.